(E)-2-[(4-Iodophenyl)iminomethyl]-6-methylphenol
نویسندگان
چکیده
The title compound, C(14)H(12)INO, adopts the phenol-imine tautomeric form. The dihedral angle between the aromatic rings is 20.6 (3)°. The mol-ecular conformation is stabilized by an intra-molecular O-H⋯N hydrogen bond while in the crystal, weak inter-molecular C-H⋯O hydrogen bonds link the mol-ecules into a zigzag chain parallel to the b axis.
منابع مشابه
2-((Z)-{3-[(Z)-(2-Hydroxy-5-methylbenzylidene)amino]-2,2-dimethylpropyl}iminomethyl)-4-methylphenol
In the title compound, C(21)H(26)N(2)O(2), the dihedral angle between the two benzene rings is 73.47 (16)°. Strong intra-molecular O-H⋯N hydrogen bonds generate S(6) ring motifs. The substituted benzene rings are twisted around the central quaternary C atom in opposite directions, making a vault geometry.
متن کامل2-[(2,4-Dimethylphenyl)iminomethyl]-6-methylphenol
The title compound, C(16)H(17)NO, is a Schiff base which adopts the phenol-imine tautomeric form in the solid state. The mol-ecule is almost planar, with a dihedral angle of 4.61 (4)° between the aromatic rings. The molecular structure is stabilized by an intramolecular O-H⋯N hydrogen bond which generates a six membered ring.
متن کامل2-[(2-Bromophenyl)iminomethyl]-6-methylphenol
In the title compound, C(14)H(12)BrNO, is a Schiff base which adopts the phenol-imine tautomeric form in the solid state. The dihedral angle between the two aromatic rings is 34.26 (9)° and an intra-molecular O-H⋯N hydrogen bond generates an S(6) ring.
متن کامل(E)-2-[(2-Chlorophenyl)iminomethyl]-4-methylphenol
The mol-ecule of the title compound, C(14)H(12)ClNO, adopts the enol-imine tautomeric form, with an intra-molecular O-H⋯N hydrogen bond. In the mol-ecule, the two benzene rings are twisted with respect to each other by 30.6 (2)°. The crystal structure is stabilized by inter-molecular C-H⋯π inter-actions.
متن کامل2-[(E)-(5-Chloro-2-methylphenyl)iminomethyl]-4-methylphenol
In the mol-ecule of the title Schiff base compound, C15H14ClNO, the two benzene rings are twisted with respect to each other, with a dihedral angle of 35.0 (3)°; an intra-molecular O-H⋯N hydrogen bond occurs. In the crystal, weak C-H⋯π inter-actions between methyl groups and chloro-phenyl rings link the mol-ecules into supra-molecular chains running along the a axis.
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